The discovery links microscopic crystal arrangements to macroscopic magnetic phenomena, improving models of ice‑giant interiors and aiding exoplanet characterization. It also showcases XFEL facilities’ capability to study matter at extreme conditions.
Superionic water occupies a niche at the intersection of solid‑state physics and planetary science. Under pressures exceeding a million atmospheres and temperatures of several thousand kelvin, water’s oxygen atoms lock into a crystalline lattice while hydrogen ions become highly mobile, giving the material metallic‑like conductivity. First predicted in the 1980s and reproduced in the laboratory in 2018, this exotic phase is thought to dominate the deep interiors of ice giants such as Neptune and Uranus, where conventional molten‑iron dynamos are absent. Understanding its structure is therefore essential for interpreting the magnetic signatures of these worlds.
To probe this elusive state, SLAC’s Matter in Extreme Conditions instrument and the Linac Coherent Light Source paired ultrafast X‑ray pulses with laser‑driven shock waves, recreating the extreme pressure‑temperature regime of ice‑giant cores. Complementary experiments at the European XFEL confirmed the observations, revealing diffraction patterns that could not be assigned to a single lattice. Instead, signatures of body‑centered cubic, face‑centered cubic and hexagonal close‑packed arrangements appeared concurrently, indicating that superionic water can sustain mixed packing structures without a sharp phase boundary. This blurring of structural lines is unprecedented among known materials.
The coexistence of multiple lattices provides a natural explanation for the chaotic, multipolar magnetic fields measured by Voyager 2, as each packing geometry influences hydrogen ion mobility and thus electrical conductivity in distinct ways. Incorporating these mixed‑phase properties into dynamo models will refine predictions of magnetic field morphology for both Solar System ice giants and the growing catalog of exoplanets with similar bulk compositions. Future work aims to directly measure conductivity for each structure and to explore how impurities such as ammonia or methane modify the superionic behavior, opening new avenues for high‑energy‑density physics and planetary exploration.
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