Cellulose Nanofibril‐Filled Damping and Lubricating Hydrogels for Mitigating Friction‐Induced Vibration of Polyurethane Composites
Researchers introduced a multi‑crosslinked polyvinyl alcohol hydrogel reinforced with carboxylated cellulose nanofibers (MCPH) and blended it into thermoplastic polyurethane. The hydrogel supplies both hydration lubrication and reversible bonding that dissipates mechanical energy, dramatically improving the composite’s friction and damping behavior. Under aqueous conditions the TPU/MCPH material recorded a coefficient of friction as low as 0.109 and showed pronounced reductions in vibration and acoustic emission. This approach offers a scalable route to high‑performance, water‑lubricated polymer components.
Impact of Device Architecture on Proton Detection Efficiency in 2D Perovskite Thick Film Detectors
Researchers compared planar and stacked architectures for 2D perovskite thick‑film detectors targeting 5 MeV protons. The stacked configuration, featuring a vertical electric field, delivered superior charge collection, higher sensitivity, and stable, energy‑independent response across 3–5 MeV. Experiments spanning fluxes from 10⁸ to...
A Customizable Perovskite Quantum Dots Platform for Visual Fluorescent Discrimination of Molecular Homologs and Enantiomers
Researchers have created a customizable fluorescence platform using chiral polymer‑coated perovskite quantum dots (CsPbBr3@PAAR/PAAS). The system delivers quasi‑mirror symmetric emission, allowing naked‑eye discrimination of (R)- and (S)-2‑butanol enantiomers. The achiral counterpart (CsPbBr3@PAA) differentiates C1–C4 monohydric alcohols, sulfoxides, and formamides through...
Designing with Li2S in Lithium–Sulfur Batteries: From Fundamental Chemistry to Practical Architectures
The perspective outlines how Li2S‑based lithium‑sulfur batteries are reshaping cell design by tackling sulfur’s insulating nature and polysulfide shuttling. It highlights atomic‑level catalytic engineering, hierarchical carbon scaffolds, and electrolyte‑solvation co‑design as levers to activate Li2S and achieve reversible cycling. These...
Liquid NaK‐Enabled Strategy for the Facile and Scalable Synthesis of Porous Fe/Co/Ni‐Based Materials for Magnetically Enhanced OER Catalysis
Researchers have introduced a room‑temperature liquid NaK‑enabled alloy‑to‑alloy method to produce porous, multiphase Fe/Co/Ni magnetic electrocatalysts. The process avoids high‑temperature calcination and toxic etchants, delivering yields above 80 % and enabling solvent recovery. The resulting amorphous materials exhibit mesoporosity up to...
Determination of Nucleation Process and Spherical Micelle Growth by Time‐Resolved SAXS During PISA: Evidence From Liquid Crystalline Spherical Nanoparticles
Researchers employed time‑resolved small‑angle X‑ray scattering (TR‑SAXS) to monitor polymerization‑induced self‑assembly (PISA) of liquid‑crystalline spherical micelles. The data reveal that nucleation occurs early and particle growth proceeds through a structural shift from interdigitated to non‑interdigitated core conformations, a shift governed...
D‐Band Modulation by Elements Synergistic Design for High‐Performance Zinc Air Batteries
Researchers engineered ultrafine high‑entropy nitride (HEN) nanoparticles that exploit elemental synergy to shift the d‑band center, accelerating *OH adsorption and desorption. Tungsten plays a pivotal role by reconstructing the electronic environment of the other metals. The resulting catalyst delivers an...
Bifunctional Cu–Sn Oxides for Electrocatalytic Upgrade of Nitrate and Glucose to Ammonium Formate
Researchers have introduced a bifunctional Cu‑Sn oxide catalyst that simultaneously drives nitrate reduction and glucose oxidation in a paired electrochemical cell. The catalyst delivers an NH₃ yield of 26.57 mg h⁻¹ cm⁻² with 85.3% Faradaic efficiency, while generating formate at 44.88 mg h⁻¹ cm⁻² and 81.8%...
Tuning Charge Storage in Bimetallic CoV–LDH for High‐Performance Supercapacitor: A Synergistic Experimental and Machine Learning Approach
Researchers employed a controlled partial‑reduction protocol to introduce oxygen vacancies into cobalt‑vanadium layered double hydroxides (CoV‑LDH). Density functional theory showed that these vacancies narrow the bandgap and increase electronic states near the Fermi level, boosting conductivity. Machine‑learning models linked synthesis...
Nanocomposite Cellulose Membranes for High‐Performance Water Evaporation Electricity Generation
Researchers at Nanjing University of Aeronautics and Astronautics have created a nanocomposite cellulose membrane for hydrovoltaic electricity generation. By depositing bismuth oxyiodide (BiOI) nanoparticles onto cellulose nanofibers via a two‑step liquid‑vapor method, the membrane achieves an open‑circuit voltage of ~3.7 V,...
Deconstruction Engineering of Lignocellulosic Biomass for the Preparation of High‐performance Hard Carbon Anode Materials in Sodium‐Ion Batteries
Researchers introduced a low‑corrosive maleic‑acid hydrothermal pretreatment to selectively strip hemicellulose from coconut shells, enriching lignin and cellulose while recovering xylose and furfural. The resulting hard‑carbon precursor exhibits a reduced closed‑pore size (1.64 nm) and increased closed‑pore volume (0.236 cm³ g⁻¹) after carbonization....
Liquid Metal‐Architected Thermal Management Materials: Void Engineering for Simultaneous High Thermal Conductivity and Flame Retardancy
Researchers have introduced liquid‑metal‑architected silicone composites that use mechanochemical encapsulation of aluminum nitride with eutectic gallium‑indium to eradicate processing‑induced voids. The void‑free architecture creates continuous thermal pathways, delivering 4.60 W m⁻¹ K⁻¹ in‑plane and 5.27 W m⁻¹ K⁻¹ out‑of‑plane conductivity at just 50 vol.% filler loading. Simultaneously,...
Beyond Thin Stacks: Physics, Materials, and Architectures of Thick Perovskite Light‐Emitting Diodes
The review outlines how thick perovskite light‑emitting diodes—ranging from 100 nm to several micrometers—offer distinct physics, material, and architectural advantages over conventional thin stacks. By increasing the emitter‑metal separation, these devices suppress plasmonic loss, boost photon‑recycling, and achieve higher out‑coupling efficiency....
Dual Enhancement of Electrochemical Ozone Production and Chlorine Evolution Reaction over Sulfur‐Doped 3D Ni‐Sb‐SnO2 Electrodes
Researchers introduced sulfur into a three‑dimensional Ni‑Sb‑SnO2 (DLS‑NATO/TiF) electrode, creating a dual‑function catalyst for electrochemical ozone production (EOP) and chlorine evolution reaction (CER). The sulfur‑doped electrode achieved a Faradaic efficiency of 50.10% for ozone and 95.70% for chlorine under acidic...
Beyond the Chill: Emerging Electrolytes, Cathodes, and Air Electrodes for Cryogenic Aqueous Zn Batteries
The review surveys recent breakthroughs in cryogenic aqueous zinc batteries, focusing on electrolyte engineering, cathode design, anode stabilization, and separator modification. Researchers have introduced liquid, suspension, and gel polymer electrolytes that disrupt hydrogen‑bond networks and improve Zn2+ solvation, enabling operation...
Low Temperature MOCVD Synthesis of High‐Mobility 2D InSe
Researchers have demonstrated low-temperature, wafer-scale metal-organic chemical vapor deposition (MOCVD) of phase-pure two-dimensional indium selenide (InSe) on c-plane sapphire. By systematically varying the Se/In precursor ratio and growth temperature, they mapped the In-rich to Se-rich InxSey phase space and identified...
Miniaturized Self‐Powered Perovskite Spectrometer
Researchers have built a miniaturized perovskite spectrometer that uses only eight self‑powered photodetectors to deliver high‑resolution spectral data. The device achieves a peak external quantum efficiency of 75% and resolves wavelengths at ~5 nm across the 680–800 nm band. By leveraging compressive‑sensing...
Anion Component Engineering of Spontaneous Perovskite Passivators for Energy Alignment Modulations in Perovskite Solar Cells
Researchers introduced n‑octylammonium bis(fluorosulfonyl)imide additives (OA‑FSI, OA‑TFSI, OA‑PFSI) to the spiro‑OMeTAD hole‑transport layer of perovskite solar cells. The anion component of these additives modulates the ionization energy of the HTM, shifting energy levels and improving charge extraction. Larger C‑F groups...
Fully Printed and Integrable Zn‐Ag Battery‐Hierarchical Sensor for Scalable Manufacturing of Monolithic Wearables
Researchers demonstrated a fully printed zinc‑silver (Zn‑Ag) battery paired with a hierarchical pressure sensor using screen‑printing technology. A mild ZnCl2 electrolyte curtails cathode dissolution, boosting battery stability, while the sensor’s multi‑scale structure delivers a record‑high sensitivity of 413.03 kPa⁻¹. The two...
Boosting Piezoelectric Catalytic H2O2 Production in Pure Water of Graphitic Carbon Nitride via Defect Engineering With Tunable Oxygen‐Doping
Researchers introduced tunable oxygen defects into graphitic carbon nitride (g‑C₃N₄) via a one‑step co‑calcination process, creating a metal‑free piezoelectric catalyst that converts mechanical energy into hydrogen peroxide. The optimized material, designated CN‑40, achieves a H₂O₂ production rate of 671 µmol g⁻¹ h⁻¹, roughly...
Integrated Single‐Atom and Cluster Catalysts for Electrocatalytic Hydrogen Energy Technologies: Current Achievements and Challenges
The review highlights integrated single‑atom and cluster catalysts (ISACCs) as a breakthrough for electrocatalytic hydrogen technologies. By coupling atom‑level precision with multi‑site reactivity, ISACCs dramatically improve the kinetics of HER, OER, ORR and HOR while cutting dependence on scarce platinum‑group...
Spin Density Modulation by Ru Nanoparticles in ZIF‐67 Framework for Magnetically Enhanced Water Splitting Reaction
Researchers engineered a Ru nanoparticle‑decorated ZIF‑67 framework (RuNP/ZIF‑67) that reshapes cobalt oxidation states and boosts spin density, inducing ferromagnetism. The magnetic catalyst, tested under a 240 mT field, cuts the hydrogen evolution reaction overpotential from 68 mV to 51 mV and the oxygen...
Low Temperature Site‐Specific Pulsed Laser Annealing of MoS2
The study introduces a non‑thermal, ultrashort pulsed laser annealing technique that selectively modifies CVD‑grown MoS2 thin films at fluences below 12 mJ cm⁻², well under the damage threshold. High‑overlap laser scanning on SiO₂‑Si substrates converts amorphous regions to crystalline MoS2, as confirmed...
Ga‐Assisted Free‐Standing Growth of CsPbBr3 Nanowires for High‐Performance Optoelectronic Applications
Researchers have developed a gallium‑assisted method to directly grow free‑standing CsPbBr3 nanowires, allowing easy transfer onto any substrate. The transferred nanowires act as high‑Q optical cavities, achieving single‑mode lasing with a polarization ratio of 0.908. Integrated photodetectors based on these...
Stress Engineering in Flexible Thermoelectrics
Flexible thermoelectric generators (F-TEGs) are emerging as a viable route to harvest low‑grade heat from both flat and irregular surfaces. The review highlights stress engineering as a pivotal technique to reconcile the long‑standing trade‑off between thermoelectric efficiency and mechanical pliability....
Enzyme‐Activated Programmable Theranostic Platform for Spatiotemporal Imaging of Intracellular MicroRNA and On‐Demand Manipulation‐Mediated Therapy
Researchers have engineered a cerium‑based metal‑organic framework (Ce‑MOF) loaded with DNA hairpins that responds to intracellular APE1 and miRNA‑21. The dual activation triggers a hybridization chain reaction, producing a Cy3‑Cy5 FRET signal for spatiotemporal imaging of miRNA expression in living...
Design Principles and Experimental Evidence for Semiconducting Heusler Thermoelectrics by Vacancy‐Filling
Researchers applied a vacancy‑filling strategy to selectively occupy 4d sites in Heusler alloys, creating an energy gap between occupied t2g and empty eg states while dramatically reducing lattice thermal conductivity to 2.77 W·m⁻¹·K⁻¹ at room temperature. The TiFeₓCoᵧSb system, constrained by...
Ultrathin and High‐Efficiency Passive Daytime Radiative Cooling Coating via Polymer‐Particle Co‐Design
Researchers have created an ultrathin passive daytime radiative cooling (PDRC) coating using a polymer‑particle co‑design approach. By matching functional‑group resonances and applying Lorenz‑Mie scattering theory to size particles, the coating reaches 93.8 % solar reflectance and 97.1 % mid‑infrared emissivity. The film...
Nanoengineering‐Based Strategies for Enhancing Dynamic Therapy
Dynamic therapy, a ROS‑driven cancer treatment, is gaining traction for its high efficacy and low systemic toxicity. Recent nanoengineering advances focus on redesigning sensitizer nanostructures, deploying sophisticated nanocarriers, and modulating the tumor microenvironment to boost reactive oxygen species production. The...
Efficient, Reversible Lead Adsorption in a Thiol‐Decorated Zirconium‐Metal–Organic Framework
Researchers have introduced a zirconium‑based metal‑organic framework (Zr‑DMSA) functionalized with thiol groups that captures lead(II) ions from water with high efficiency. The material leverages mixed sulfur/oxygen chelation via flexible dangling ligands, as confirmed by solid‑state NMR and pair‑distribution function analyses....
Triboelectric Capacitance Supplementation in Energy Storage Composites with Functionalized Carbon Fiber Electrodes
Researchers demonstrate that surface‑functionalized carbon‑fiber electrodes combined with electrospun polymer nanofiber separators can substantially boost the performance of structural supercapacitors. The triboelectric effect at the carbon‑fiber/separator interface generates additional charge, while a hybrid piezo‑triboelectric layer further raises voltage and specific...
Multifunctional Superwetting Sea‐Urchin‐Mimetic Nanosheet‐Based Interface for Remote Oil‐Water Separation
Researchers have developed a fluorine‑free, barium carbonate‑functionalized reduced graphene oxide (FBC‑rGO) coating that exhibits superhydrophobic (water contact angle >154°) and superoleophilic properties, enabling rapid oil uptake of 15‑65 g per gram and >97% separation efficiency. The coating’s hierarchical sea‑urchin‑like nanostructure stabilizes...
Engineering Metastability in Atomic Layer Deposition: Polymorph and Valence Control
The review outlines how atomic layer deposition (ALD) can be engineered to access metastable material phases, focusing on structural polymorphs and multivalence states. It details strategies such as temperature modulation, substrate lattice matching, grain‑size control, doping, solid‑solution formation, and precursor...
Lewis Acid‐Base Effects on Molecular Structure and Charge Density in Solid Polymer Electrolytes for Solid‐State Batteries
Researchers examined solid polymer electrolytes (SPEs) based on PVDF‑HFP incorporating LiFSI, LiTFSI, and a 1:1 binary mixture. They found that salt polarity and Lewis basicity dictate dehydrofluorination, crystallinity, and charge density, directly influencing ionic conductivity and mechanical robustness. The binary...
Dynamic Adsorption of Molybdate Promoted Self‐Optimization and Self‐Healing of NiFe/NiMo in Alkaline Water Electrolysis
Researchers have engineered a NiFe/NiMo heterojunction catalyst that delivers exceptional bifunctional performance in alkaline water electrolysis. The material achieves 100 mA cm⁻² at only 99 mV overpotential for the hydrogen evolution reaction (HER) and 233 mV for the oxygen evolution reaction (OER). Free molybdate...
Real‐Time In Vivo Detection of Nanocarrier Number and Velocity in the Cerebrovasculature Using Hot Band Absorption
The study introduces DNA‑stabilized silver nanoclusters (DNA640) that emit anti‑Stokes fluorescence via hot‑band absorption, encapsulated in cationic mesoporous silica nanoparticles and coated with liposomes for enhanced brightness and chloride resistance. Using adeno‑associated virus‑driven albumin‑mNeonGreen to label mouse cerebrovasculature, researchers combined...
Size‐Dependent Effect of Ni Nanoparticles Confined in Ni‐Modified Flower‐Like Carbon Toward CO2 Electroreduction Reaction
Researchers engineered a flower‑like nitrogen‑doped carbon framework to confine nickel species, enabling coexistence of Ni‑N‑C sites and size‑controlled Ni nanoparticles. Moderate Ni loading (0.2–1 mmol) stabilized small particles, delivering a CO faradaic efficiency of ~90% at –1.0 V vs RHE and maintaining...
Comparative WS2‐NbS2 and MoS2‐NbS2 Binary Alloy Nanosheets as Excellent Hydrogen Evolution Reaction Electrocatalysts
Researchers synthesized binary alloy nanosheets W1‑xNb xS2 and Mo1‑xNb xS2 via colloidal routes, achieving uniform atomic mixing across the full composition range. Incorporating niobium transforms the semiconducting WS2 and MoS2 into a more metallic phase, which DFT calculations confirm. In...
Flexoelectric Polarization Control via Defect‐Driven Strain Gradients in Complex Oxide Thin Films
Researchers have demonstrated deterministic control of in‑plane flexoelectric polarization in epitaxial LaAlO₃ thin films by engineering oxygen‑vacancy gradients. Electrically written vacancy‑rich lines induce localized lattice expansion, generating converging strain gradients that produce a strong shear‑type electromechanical response observed via lateral...
Confinement and Self‐Supply of Carbon Sources by Micro‐Containers Enable Efficient In Situ Growth of Carbon Nanotubes for Li‐Ion Storage
Researchers have introduced a scalable method that uses expanded graphite micro‑containers to confine carbon and nitrogen precursors, enabling rapid in situ growth of nitrogen‑doped carbon nanotubes (N/CNTs). The confined environment supplies sufficient carbon/nitrogen locally, achieving a high yield (>14%) and...
Toward Stable Mn Metal Anodes and Electrolyte Design for Mn‐Based Batteries
Manganese metal anodes promise higher capacity and a lower redox potential than zinc, positioning them as a next‑generation battery candidate. However, rapid hydrogen evolution, corrosion, and dendritic growth have limited practical deployment. Recent research highlights concentrated aqueous electrolytes, halogen‑mediated non‑aqueous...
Mechanically Robust and Anti‐Biofouling Hybrid Encapsulation via Layered Organic–Liquid Interfaces for Implantable Devices
Researchers introduced a Multi‑layered Organic‑based Liquid Encapsulation (MOLE) that merges amine‑functionalized silicone elastomer with Parylene‑C to protect implantable bioelectronics. The outer silicone layer, infused with silicone oil, cuts protein adsorption to under 1% and repels biofilm formation. MOLE delivers an...
High‐Conductive Stretchable Electrode Array Patch for Real‐Time High‐Fidelity Electromyography Monitoring
Researchers unveiled a multilayer stretchable microelectrode array patch (MEAP‑S) that combines photolithographically patterned gold electrodes with an ultrathin SEBS dielectric. The device delivers conductivity above 10^5 S m⁻¹, stretches up to 100 % strain, and packs 100 channels per cm² while suppressing crosstalk....
Neutralizing Charge Centers Radius via Dipole‐Charge Interaction in Perovskites
Researchers introduced 3,3-difluoropyrrolidine hydrochloride (GOSO-005), a fluorinated dipolar molecule, to neutralize positively charged defects in organic‑inorganic perovskites. The dipole‑charge interaction reduces electron‑trapping radius, enhancing charge transport and suppressing Shockley‑Read‑Hall recombination. Devices incorporating GOSO-005 achieved a certified power conversion efficiency of...
Nanocatalytic Mitochondrial Oxidative Stress Amplification and Mitophagy Disruption for Efficient Tumor Catalytic Therapy
Researchers have engineered a mitochondria‑targeted nanocatalyst, Co‑SA‑TPP@CQ, that couples cobalt single‑atom catalysis with triphenylphosphine localization and chloroquine co‑delivery. Once inside tumor mitochondria, the catalyst produces superoxide anions and oxygen, disrupting the electron transport chain and creating a self‑sustaining oxidative‑stress amplification...
Activating High‐Loading Cathodes Using Percolative Graphite in Rechargeable Alkaline Zn–MnO2 Batteries
Researchers introduced percolative graphite (PG), a moderate‑surface‑area conductive additive, to address the insulating nature of MnO2 in rechargeable alkaline Zn–MnO2 batteries. By replacing large amounts of low‑surface‑area graphite or reactive nanocarbons, PG forms an effective conductive network while maintaining high...
Self‐Generated Chemical Gradients for Controlling the Locomotion of Artificial Nanomotors
Researchers have engineered lipase‑activated nanomotors that generate their own chemical gradients to drive motion in ion‑rich aqueous environments. By hydrolyzing acylated dextran, the motors release carboxylate fragments that accumulate at the particle interface, creating localized concentration differences that propel the...
Multifunctional Hybridized Local and Charge‐Transfer Small Molecular Fluorophore for Imaging‐Guided Photodynamic Anticancer Therapy
Researchers have engineered a D‑π‑A‑π‑D small molecule, XSOTA, that exhibits hybridized local and charge‑transfer (HLCT) excited‑state behavior. This HLCT architecture delivers an exceptional fluorescence quantum yield of 89.2% and a reactive oxygen species (ROS) generation efficiency of 56.3%. When formulated...
Multifunctional Oral Hydrogel Containing Dual‐Active Pt/Mn3O4 Nanozyme for Synergistic Pyroptosis Suppression and Gut Microenvironment Reprogramming to Alleviate Radiation Intestinal Injury
Researchers have engineered an oral hydrogel, PMC@Gel, that co‑encapsulates a Pt/Mn3O4 nanozyme and curcumin to treat radiation‑induced intestinal injury. The nanozyme provides catalase‑ and SOD‑like activity, rapidly scavenging reactive oxygen species, while curcumin restores autophagy and modulates inflammation. The pH‑responsive...
Decoding the Oxygen Evolution Reaction Mechanism in a Novel Octanuclear Nickel(II) Double Cubane Cluster: Unleashing the Electrocatalytic Performance
Researchers synthesized a novel octanuclear nickel(II) double cubane cluster using a Schiff‑base ligand and confirmed its structure by single‑crystal X‑ray diffraction. When immobilized on activated carbon cloth (CC‑3), the catalyst achieved a low OER overpotential of 290 mV at 10 mA cm⁻² in...
